Syntheses, Reactivity, Structures, and Dynamic Properties of Gyroscope-like Iron Carbonyl Complexes Based on Dibridgehead Diarsine Cages
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چکیده
منابع مشابه
Osmium–Germanium and Osmium–Germanium–Gold Carbonyl Cluster Complexes: Syntheses, Structures, Bonding, and Reactivity
Reactions of Os3(CO)10(NCMe)2 with HGePh3 have yielded the compounds Os3(CO)10(NCMe)(GePh3)(μ-H) (1) and Os3(CO)10(GePh3)2(μ-H)2 (2) by the sequential replacement of the NCMe ligands and the oxidative addition of the GeH bonds of one and two HGePh3 molecules, respectively, to the osmium atoms of the cluster. Compound 2 exists as two isomers in solution at low temperatures which interconvert rap...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2016
ISSN: 0276-7333,1520-6041
DOI: 10.1021/acs.organomet.6b00447